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Abstract The geographic center of El Niño has shifted from the tropical eastern Pacific (EP) in the 20th century to the tropical central Pacific (CP) in the 21st century. Analyzing data spanning 1948–2018, this study uncovers notable alterations in the impact of the changing El Niño patterns on California market squid (Doryteuthis opalescens) landings. While the traditional EP El Niño in the 20th century significantly reduces squid landings, this impact diminishes with the ascent of the CP type of El Niño in the 21st century. Remarkably, the CP‐I type of El Niño, a specific variant where warming occurs predominantly in the central Pacific and is often less intense but more frequent than traditional El Niño events, can even amplify squid landings. These transformations stem from variations in sea surface temperature, trade winds, and Sverdrup transport associated with different El Niño types. These findings suggest that the fishery community should consider developing adaptive approaches to address the evolving impacts of El Niño. 

Abstract The Indian and Pacific Oceans surround the Maritime Continent (MC). Major modes of sea surface temperature variability in both oceans, including the Indian Ocean Dipole (IOD) and El Niño–Southern Oscillation (ENSO), can strongly affect precipitation on the MC. The prevalence of fires in the MC is closely associated with precipitation amount and terrestrial water storage in September and October. Precipitation and terrestrial water storage, which is a measurement of hydrological drought conditions, are significantly modulated by Indian Ocean Dipole (IOD) and El Niño events. We utilize long-term datasets to study the combined effects of ENSO and the IOD on MC precipitation during the past 100 years (1900–2019) and find that the reductions in MC precipitation and terrestrial water storage are more pronounced during years when El Niño and a positive phase of the IOD (pIOD) coincided. The combined negative effects are produced mainly through an enhanced reduction of upward motion over the MC. Coincident El Niño-pIOD events have occurred more frequently after 1965. However, climate models do not project a higher occurrence of coincident El Niño-pIOD events in a severely warming condition, implying that not the global warming but the natural variability might be the leading cause of this phenomenon. 

Despite the enormous developments in asymmetric catalysis, the basis for asymmetric induction is largely limited to the spatial interaction between the substrate and catalyst. Consequently, asymmetric discrimination between two sterically similar groups remains a challenge. This is particularly formidable for enantiodifferentiation between two aryl groups without a directing group or electronic manipulation. Here we address this challenge by using a robust organocatalytic system leading to excellent enantioselection between aryl and heteroaryl groups. With versatile 2-indole imine methide as the platform, an excellent combination of a superb chiral phosphoric acid and the optimal hydride source provided efficient access to a range of highly enantioenriched indole-containing triarylmethanes. Control experiments and kinetic studies provided important insights into the mechanism. DFT calculations also indicated that while hydrogen bonding is important for activation, the key interaction for discrimination of the two aryl groups is mainly π–π stacking. Preliminary biological studies also demonstrated the great potential of these triarylmethanes for anticancer and antiviral drug development. 

Abstract During the past two decades, the Maritime Continent (MC) has experienced increased deforestation. Here we show, with ensemble idealized deforestation experiments, that the MC deforestation could potentially alter the complexity (i.e., event‐to‐event differences) of the El Niño‐Southern Oscillation (ENSO) in terms of its spatial pattern and temporal evolution. The deforestation model run increases the occurrences of the Central Pacific and multi‐year types of ENSO compared to the control experiments. This change in ENSO complexity can be attributed to MC's intensification of the subtropical ENSO dynamics, commonly known as the seasonal footprinting mechanism. The deforestation amplifies the mean state of the subtropical high over the northeastern Pacific, leading to an increased dominance of subtropical ENSO dynamics in determining the ENSO pattern and evolution. This idealized coupled climate modeling study suggests that MC deforestation has a potential to alter ENSO's complexity, making El Niño more complex and less predictable.